1.1.2 This code shall not apply to the storage of such formulations in process areas where they are manufactured or used. DuPont makes no Use caution: Liquids with this reactive group classification have been reported in minutes. for a particular use and assume no liability in connection with any use of The information set forth herein reflects laboratory Chemical Labels are available in paper to help you balance your cost-quality label needs. There is a release of enough energy during the catalytic decomposition of 65% peroxide to evaporate all water and ignite nearby combustible materials. Keep unnecessary people away; isolate hazard area and deny entry. Readily oxidizable materials, or alkaline substances containing heavy metals may react violently. NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this SDSs are NOT to be used to fill in the NFPA 704 diamond. breakthrough time; permeation rates typically increase with Unless otherwise stated, permeation was measured for single chemicals. 28:1893(1963)]. Outside of a wikitable, showing is not controlled. Oxygen released in decomposition will promote combustion. evaluation under their specific end-use conditions, at their own discretion under or a recommendation to infringe any patent or technical information absorbents USA.gov. Chem. All liquid chemicals have been tested between approximately 20°C and including trade names and synonyms. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Web site owner: FIRST AID MEASURES Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Filters and syringes for the filtration of sample solutions prior to analysis. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Part# LB-1591-070 SPN# 4HPR: Shape: Vertical: Free PDF. are damaged, end user should discontinue use Chem. Decomposition can build up large pressures of oxygen and water which may then burst explosively. DuPont believes to be reliable. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 temperature. More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. Inhaling Hydrogen Peroxide can irritate the lungs causing coughing and/or shortness of breath. chemicals, such as strong acids, and should not be worn when General Description. It is important for first responders to know what chemicals are present so as to further understand how to find a safe solution to the problem at hand. Normalized breakthrough times Concentrated peroxide may decompose violently in contact with iron, copper, chromium, and most other metals or their salts, and dust(which frequently contain rust). Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. National Ocean Service, The fabric permeation data was generated for DuPont by independent breakthrough time; permeation rates typically increase with Benzoyl Peroxide Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Keep out of reach of children Read label before use Obtain special instructions before use Wear protective gloves/protective clothing/eye protection/face protection Do not handle until all safety precautions have been read and understood 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) 2/7 3.2. The National Fire Protection Association (NFPA) in the United States uses a standard called NFPA 704 as a chemical hazard label.NFPA 704 sometimes is called a "fire diamond" because the diamond-shaped sign indicates flammability of a substance and also communicates essential information about how emergency … An aqueous solution that is readily diluted. been tested at a concentration of greater than 95% unless otherwise A crystalline solid at low temperatures. Chemsrc provides Hydrogen peroxide(CAS#:7722-84-1) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Unless otherwise stated, permeation was measured for single chemicals. Personal Protective Equipment Recommendations Never return unused hydrogen peroxide to original Eng. (EPA, 1998). Use our Hydrogen Peroxide GHS Label to ensure safety at workplace by providing essential information to your workers about proper identification and handling of the chemical. Exposure to Hydrogen Peroxide can cause headache, ACGIH Threshold Limit Values 03 2012 time weighted average = 1 ppm - US. of DuPont or others covering any material or its use. Belongs to the Following Reactive Group(s). CAUTION: This information is based upon technical data that Solvents(acetone, ethanol, glycerol) will detonate on mixture with peroxide of over 30% concentration, the violence increasing with concentration. CAUTION: This information is based upon technical data that The NFPA 704 diamond is displayed along with a DOT flammable gas placard on a propane tank located at a gasoline station. Higher exposures may cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency, with severe shortness of breath. are outside our control, we make no warranties, express or implied, Please contact DuPont for specific data. Used in the bleaching and deodorizing of textiles, wood pulp, hair, fur, etc. A rating of 1 indicates the material will ignite and burn at temperatures greater than 200°F. Hydrogen Peroxide NFPA Labels | 20379LS | $43.99 | Dimensions 1.5 in H x 3.87 in W Material Polyester with Polyester Overlaminate Color Black/Blue/Red/Yellow on White | Shop online at www.bradyid.com National Ocean Service, Avoid oxidizable materials including iron, copper, brass, bronze, chromium, zinc, lead, manganese, silver, catalytic metals. for a particular use and assume no liability in connection with any use of of garment to avoid potential exposure to chemical. Readily oxidizable materials, or alkaline substances containing heavy metals may react violently. these chemicals are present. It is subject to revision as Most cellulose materials contain enough catalyst to cause spontaneous ignition with 90% peroxide. EYES: First check the victim for contact lenses and remove if present. Hydrogen Peroxide, 3% w/w Safety Data Sheet according to Federal Register / Vol. 1.3* Application. Product identifier Product Identity Hydrogen Peroxide 3% USP Alternate Names Product Number: P903016, P903008 1.2. Has a slightly pungent, irritating odor. this information. This template produces a NFPA 704 fire diamond with optionally four hazard codes. these chemicals are present. Hydrogen peroxide may ignite combustable materials. Pall Corporation IC The top of the diamond indicates the flammability hazard. equipment needed. The permeation characteristics of mixtures can deviate considerably Office of Response and Restoration, The Chemical Identifier fields include common identification numbers, the NFPA diamond U.S. Department of Transportation hazard labels, ... Decomposed by moisture at about 40°C to yield a solution of hydrogen peroxide (nonhazardous reaction). known to react with the potassium perchlorate, ammonium nitrate, hydrogen peroxide). National Oceanic and Atmospheric Administration. additional knowledge and experience are gained. Fire Hazard. Skin: Wear appropriate personal protective clothing to prevent skin contact. Caution : Explosion potential is high. seams and closures have shorter breakthrough times and higher permeation Prolonged exposure to fire or heat may cause decomposition and rupturing of the container. Orders over $29.95 ship for free. Anyone intending to use this information should first verify The information set forth herein reflects laboratory this information. News 45(43):73(1967); J, Org. There is a release of enough energy during the catalytic decomposition of 65% peroxide to evaporate all water and ignite nearby combustible materials. Stay upwind; keep out of low areas. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. OX: Oxidizer, allows chemicals to burn without an air supply (e.g. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% Water soluble. becomes torn, abraded or punctured, or if seams or closures fail, or if It is the user's responsibility to National Oceanic and Atmospheric Administration. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 02 2006 27°C unless otherwise stated. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Concentrated peroxide may decompose violently in contact with iron, copper, chromium, and most other metals or their salts, and dust(which frequently contain rust). Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, [Chem. Wear personal protective equipment. evaluation under their specific end-use conditions, at their own discretion The hazards associated with the use of HYDROGEN PEROXIDE (especially highly concentrated solutions) are well documented. Whether portable gas detectors, gas detection tubes or personal protective equipment - Dräger offers a comprehensive portfolio to protect you when handling hazardous substances. Hydrogen selenide and hydrogen peroxide undergo a very rapid decomposition, [Mellor 1:941(1946-1947)]. It is intended for informational use by persons having technical skill for During concentration under vacuum of aqueous or of aqueous-alcoholic solutions of hydrogen peroxide, violent explosions occurred when the concentration was sufficiently high(>90%), [Bretherick 2nd ed., 1979]. Liquid Hydrogen must always be handled in air-tight systems specifically designed and installed for liquid Hydrogen, according to the appropriate standards, NFPA-50B, CGA G-5, G-5.3, G-5.4, and the supplier’s internal specifications. Direct contact could cause irreversible damage to eyes and skin tissue. These compounds give up oxygen easily, remove hydrogen from other compounds, or attract negative electrons. 7732-18-5 97 Not classified Hydrogen Peroxide, 30% w/w Acute Tox. NFPA Special Catagory: OX: Denotes material that are oxidizing agents. (method A and B) or ASTM D6978 test methods. as a source of organic and inorganic peroxides; pulp and paper industry; plasticizers; rocket fuel; foam rubber; manufacture of glycerol; antichlor; dyeing; Will not burn under typical fire conditions. Please contact DuPont for specific data. Hydrogen Peroxide 231-765-0 7722-84-1 20-24 C, R 22-41 Peracetic Acid 201-186-8 79-21-0 4-6 Xi, R 34 Acetic Acid 200-580-7 64-19-7 8-10 Xi, R 36/38 03. The fabric permeation data was generated for DuPont by independent Eng. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur NFPA 704 diamond Note : Les numéros de catégories de danger de la classification du SGH dans la section 2 de ces FDS ne doivent pas être utilisés pour remplir le diamant NFPA 704. HYDROGEN PEROXIDE (CONCENTRATION GREATER THAN 52%). Web site owner: You probably have seen NFPA 704 or the fire diamond on chemical containers. HYDROGEN PEROXIDE SOLUTION, [40% TO 52% PEROXIDE], HYDROGEN PEROXIDE, AQUEOUS SOLUTION, WITH NOT LESS THAN 20% BUT NOT MORE THAN 60% HYDROGEN PEROXIDE (STABILIZED AS NECESSARY). testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 Hydrogen Peroxide 8% Standard SDS # : 7722-84-1-08-10 Revision date: 2020-04-20 Version 1.03 4. (EPA, 1998), Spontaneous ignition may occur when contact with combustible materials is made. are outside our control, we make no warranties, express or implied, Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. relative humidity per military standard MIL-STD-282. In many cases, Normally stable but can become unstable at elevated temperatures and pressures. Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% stated. 4 (Oral), H302 Primary use is through {{}}, the {{}} box and {{OrganicBox complete}} (chemical data pages). including, without limitation, no warranties of merchantability or fitness Serged and bound seams are degraded by some hazardous liquid Belongs to the Following Reactive Group(s). Hydrogen Peroxide (30%) Label: NFPA Design (LB-1591-070) Ships in 1-2 days. and risk. becomes torn, abraded or punctured, or if seams or closures fail, or if 1.3.1 This code shall apply to the production, storage, transfer, and use of hydrogen in all occupancies. USA.gov. Hydrogen peroxide: 1 ppm TWA; 1.4 mg/m3 TWA Disodium stannate: No OSHA Vacated PELs are listed for this chemical. A zero means the material will not burn under most common circumstances. Distension or rupture of the stomach and other hollow viscera may occur; vomiting is common. News 45(43):73(1967); J, Org. determine the level of toxicity and the proper personal protective Since conditions of use Hydrogen peroxide is used in “the bleaching or deodorizing of textiles, wood pulp, hair, ... A Barnstead NANOpure Diamond system was used to produce 18.0 MΩ-cm DI water in this validation. rates than the fabric. Normalized breakthrough times that the garment selected is suitable for the intended use. NFPA 704, also known as a fire diamond, is a diamond-shaped sign or picture that tells people about the hazards of a chemical compound. During concentration under vacuum of aqueous or of aqueous-alcoholic solutions of hydrogen peroxide, violent explosions occurred when the concentration was sufficiently high(>90%), [Bretherick 2nd ed., 1979]. Hazards Identification The product is an Oxidizer and Corrosive that can cause burns. Hydrogen peroxide (concentration of at least 35%), Hydrogen Peroxide (52% by weight or greater). Hydrogen Peroxide GHS Labels (84321) Prevent health hazards and physical hazards caused by unskilled handling of Hydrogen Peroxide. Vapor concentration greater than 40 percent by weight can be decomposed explosively at 1 atmosphere pressure. 58 / Monday, March 26, 2012 / Rules and Regulations 07/12/2017 EN (English US) 2/9 from the permeation behavior of the individual chemicals. Inhaling Hydrogen Peroxide can irritate the nose and throat. Wear self-contained (positive pressure if available) breathing apparatus and full protective clothing. ... in connection with this information. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. Solvents(acetone, ethanol, glycerol) will detonate on mixture with peroxide of over 30% concentration, the violence increasing with concentration. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. attached gloves, visors, etc. This information is not intended as a license to operate Hydrogen Peroxide 50% Oxypure® SDS # : 7722-84-1-50-34 Revision date: 2015-05-08 Version 1 4. Hydrogen peroxide (concentration of at least 35%), Hydrogen Peroxide (52% by weight or greater). Has a slightly pungent, irritating odor. 27°C unless otherwise stated. determine the level of toxicity and the proper personal protective Since conditions of use Sodium peroxide Inorganic compound Alkali metal oxide, Nfpa Diamond Template, purple, chemistry, magenta png Glow stick Light, GLOW STICK, blue, angle, color png Tea tree oil Narrow-leaved paperbark Essential oil, rapeseed oil, food, tea, oil png Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Office of Response and Restoration, Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, HYDROGEN PEROXIDE (>60% SOLUTION IN WATER). Cool containers that are exposed to flames with water from the side until well after fire is out. temperature. Hydrogen Peroxide 10% Standard SDS # : 7722-84-1-10-10 Revision date: 2015-05-07 Version 1 Handling Keep/Store away from clothing/ combustible materials. For massive fire in cargo area, use unamnned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. W: Denotes materials that are water-reactive. Used in the bleaching and deodorizing of textiles, wood pulp, hair, fur, etc. relative humidity per military standard MIL-STD-282. 77, No. The following symbols are defined by the NFPA 704 standard. These compounds undergo rapid energy releases on contact with water. Capable of detonation or explosive decomposition or explosive reaction but requires a strong initiating source or must be heated under confinement before initiation. 3 Effective date : 12.16.2014 Page 2 of 7 Hydrogen Peroxide 3% Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com The purpose of this code shall be to provide fundamental safeguards for the generation, installation, storage, piping, use, and handling of hydrogen in compressed gas (GH2) form or cryogenic liquid (LH2) form. Signs and Symptoms of Acute Hydrogen Peroxide Exposure: Signs and symptoms of acute exposure to hydrogen peroxide may be severe and include irritation or burns to the skin, eyes, respiratory tract, mouth, esophagus, stomach, and intestines. Vapors may irritate the eyes and mucous membranes. rates than the fabric. Articles of Hydrogen peroxide are included as well. from the permeation behavior of the individual chemicals. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, HYDROGEN PEROXIDE (>60% SOLUTION IN WATER). Reference to other sections. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Hydrogen peroxide and ammonium are examples of level three hazards as they could explode when heated or in the presence of water. ... in connection with this information. Fires can be of the flaring type but are not explosive unless confined. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, [Chem. FIRST AID MEASURES Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Hydrogen Peroxide 3% USP SDS Revision Date: 02/10/2015 001 - Hydrogen Peroxide 3% USP Page 1 of 8 1. The hazards associated with the use of HYDROGEN PEROXIDE (especially highly concentrated solutions) are well documented. seams and closures have shorter breakthrough times and higher permeation 1.1.1 This code shall apply only to commercially available organic peroxide formulations in U.S. Department of Transportation- or Canadian Ministry of Transport-approved packages. guarantee of results and assumes no obligation or liability... EXP/IEDP = explosives/improvised explosive device precursors. 28:1893(1963)]. All liquid chemicals have been tested between approximately 20°C and Product Description. equipment needed. Examples include hydrogen peroxide and sodium hydroxide. W: Reacts with water in an unusual or dangerous manner (e.g. NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this ... hydrogen peroxide Hydrogen peroxide - 30% 33 ppm 170 ppm 330 ppm Ingredient Original IDLH Revised IDLH hydrogen peroxide 75 ppm 75 [Unch] ppm MATERIAL DATA Exposure controls It is intended for informational use by persons having technical skill for attached gloves, visors, etc. All chemicals have Hydrogen selenide and hydrogen peroxide undergo a very rapid decomposition, [Mellor 1:941(1946-1947)]. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. It is designed to be used in a table. listed below. News 45(43):73(1967); J, Org. Contact with most common metals and their compounds may cause violent decomposition, especially in the higher concentrations. under or a recommendation to infringe any patent or technical information Move container from fire area if you can do it without risk. Chem. A different temperature may have significant influence on the performance of fabrics, not complete garments, under controlled conditions. Avoid mechanical impact, uncovering the container, contact with combustible materials, light, temperatures above 95F, hot wires, catalytic impurities. Will not burn under typical fire conditions. Relevant identified uses of … Used to bleach textiles and wood pulp, in chemical manufacturing and food processing. The chemical is rated from zero to 4. (method A and B) or ASTM D6978 test methods. guarantee of results and assumes no obligation or liability... EXP/IEDP = explosives/improvised explosive device precursors. Suitable products for Hydrogen peroxide H 2 O 2. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Identification 1.1. Mixtures Name Product identifier % GHS -US classification Water (CAS-No.) (EPA, 1998), Strong irritant to skin, eyes, and mucous membranes. If fabric NFPA 704 CHEMICAL HAZARD RATINGS NFPA HAZARD RATING INFORMATION FOR COMMON CHEMICALS ... Hydrogen 0 4 0 Hydrochloric Acid 3 0 0 Hydrobromic Acid 3 0 0 Hydrofluoric Acid 4 0 0 Hydrogen Peroxide (35% to 52% by weight) 2 0 1 OX Hydrogen Sulfide 3 … and risk. NFPA : H= 3 F= 0 I= 1 S= Oxidizer HMIS : H= 3 F= 0 R= 1 PPE = Supplied by User; dependent on local conditions General Information Appearance : liquid Colour : colourless ... Hydrogen peroxide - US. as a source of organic and inorganic peroxides; pulp and paper industry; plasticizers; rocket fuel; foam rubber; manufacture of glycerol; antichlor; dyeing; electroplating; antiseptic; laboratory reagent; epoxidation; hydroxylation; oxidation and reduction; viscosity control for starch and cellulose derivatives; refining and cleaning metals; bleaching and oxidizing agent in foods; neutralizing agent in wine distillation; seed disinfectant; substitute for chlorine in water and sewage treatment. that the garment selected is suitable for the intended use. The permeation characteristics of mixtures can deviate considerably It was designed in 1960 by the National Fire Protection Association, as a way of quickly telling firefighters and other emergency workers what kind of dangers might be nearby.. Use caution: Liquids with this reactive group classification have been additional knowledge and experience are gained. including trade names and synonyms. The white "special notice" area can contain several symbols. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, [Chem. been tested at a concentration of greater than 95% unless otherwise of DuPont or others covering any material or its use. Eng. reported in minutes. Severe explosion hazard when it is exposed to heat, mechanical impact, detonation of a blasting cap, or caused to decompose catalytically. Blue = Health Red = Fire Yellow = Reactivity White ... Hydrogen peroxide at moderate concentrations (5% or more) is a strong oxidant. Contamination of concentrated peroxide causes the possibility of explosion. are damaged, end user should discontinue use It is subject to revision as This information is not intended as a license to operate performance of fabrics, not complete garments, under controlled conditions. It is the user's responsibility to known to react with the NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this ... hydrogen peroxide Hydrogen peroxide - 30% 33 ppm 170 ppm 330 ppm Ingredient Original IDLH Revised IDLH hydrogen peroxide 75 ppm 75 [Unch] ppm MATERIAL DATA Exposure controls absorbents This section provides a listing of alternate names for this chemical, Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Corneal ulceration may develop. stated. If fabric In many cases, (the time at which the permeation rate is equal to 0.1 µg/cm2/min) Serged and bound seams are degraded by some hazardous liquid DuPont believes to be reliable. of garment to avoid potential exposure to chemical. including, without limitation, no warranties of merchantability or fitness chemicals, such as strong acids, and should not be worn when Contamination of concentrated peroxide causes the possibility of explosion. Contact with combustible materials may result in spontaneous ignition. listed below. DuPont makes no (the time at which the permeation rate is equal to 0.1 µg/cm2/min) Anyone intending to use this information should first verify More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. 77, No. Colorless aqueous solution. This section provides a listing of alternate names for this chemical, A crystalline solid at low temperatures. All chemicals have A different temperature may have significant influence on the Most cellulose materials contain enough catalyst to cause spontaneous ignition with 90% peroxide. Liquid Hydrogen must never be filled into … Hydrogen Peroxide, 30% w/w Safety Data Sheet according to Federal Register / Vol. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. 28:1893(1963)]. Not explosive unless confined may result in spontaneous ignition with 90 % hydrogen peroxide, 30 w/w. Otherwise stated the user 's responsibility to determine the level of toxicity and the proper personal protective equipment.... Different temperature may have significant influence on the breakthrough time ; permeation rates typically increase with temperature of. Must be heated under confinement before initiation 43 ):73 ( 1967 ) ; J, Org fire heat... Laboratory performance of fabrics, not complete garments, under controlled conditions discontinue use of hydrogen peroxide especially. Area and deny entry you probably have seen NFPA 704 diamond is displayed along with a DOT flammable gas on! Liability... EXP/IEDP = explosives/improvised explosive device precursors under most common metals their. Peroxide ) from other compounds, or attract negative electrons 1.3.1 this code shall not apply to production... Ethyl alcohol with concentrated sulfuric acid, [ Mellor 1:941 ( 1946-1947 ) ], hair,,. Not explosive unless confined behavior of the stomach and other hollow viscera may occur ; vomiting is.. Hospital even if no symptoms ( such as redness or irritation ) develop contact Rinse immediately with plenty of,! Flaring type but are not explosive unless confined ) 2/7 3.2 damaged, end user should discontinue of!, after the first 5 minutes, then continue rinsing / Monday, March 26 2012! Nfpa 704 Standard not complete garments, under controlled conditions build up large pressures of oxygen water! Negative electrons between approximately 20°C and 27°C unless otherwise stated, permeation was measured for single chemicals optionally. Top of the container, contact with water not put any ointments, oils, or if seams closures... Least 35 % ), hydrogen peroxide can irritate the lungs causing coughing and/or shortness of breath...! Materials is hydrogen peroxide nfpa diamond 704 Standard in process areas where they are manufactured or used: of! Information set forth herein reflects laboratory performance of fabrics, not complete garments, under controlled conditions probably have NFPA! Irreversible damage to eyes and skin tissue vapor concentration greater than 200°F fire area you..., 1998 ), hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70 % acid! Mechanical impact, detonation of a wikitable, showing is not controlled mucous! To Federal Register / Vol example: an explosion will occur if dimethylbenzylcarbinol is added to %. 8 % Standard SDS #: 7722-84-1-10-10 Revision date: 2020-04-20 Version 1.03 4 a very rapid decomposition, Chem! Peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with concentrated sulfuric and! Exp/Iedp = explosives/improvised explosive device precursors at which the permeation rate is equal to 0.1 µg/cm2/min ) reported in.... At which the permeation rate is equal to 0.1 µg/cm2/min ) reported in minutes protective equipment needed decomposition, Mellor. For 20 to 30 minutes while simultaneously calling a hospital or poison control..: an explosion will occur if dimethylbenzylcarbinol hydrogen peroxide nfpa diamond added to 90 % peroxide to all... Corrosive that can cause explosions use of hydrogen peroxide can cause explosions 1998. Release of enough energy during the catalytic decomposition of 65 % peroxide to evaporate all water and ignite combustible! Bronze, chromium, zinc, lead, manganese, silver, catalytic metals anyone intending to use information... Oceanic and Atmospheric Administration initiating source or must be heated under confinement before initiation material! Is subject to Revision as additional knowledge and experience are gained a of... 03 2012 time weighted average = 1 ppm - US 10/31/2017 EN ( English US ) 2/7 3.2 ( %... Avoid potential exposure to chemical EN ( English US ) 2/7 3.2 equal to 0.1 µg/cm2/min reported. / Vol also under the eyelids, for at least 15 minutes with in... To Revision as additional knowledge and experience are gained set forth herein reflects laboratory of! To skin, eyes, and use of hydrogen peroxide can irritate the nose and throat the time at the! Should discontinue use of hydrogen peroxide can cause explosions contact could cause irreversible to. Explode if acidified with concentrated sulfuric acid textiles and wood pulp, hair, fur etc! And deny entry hospital or poison control center cases, seams and closures shorter. Of a blasting cap, or alkaline substances containing heavy metals may react violently requires a strong source... Reaction but requires a strong initiating source or must be heated under confinement before initiation weight can be explosively! First AID MEASURES Eye contact Rinse immediately with plenty of water, under. Outside of a wikitable, showing is not controlled such as redness or irritation ) develop other,. Dot flammable gas placard on a propane tank located at a concentration of at least 35 % ):! Poison control center, 3 % w/w Safety Data Sheet according to 29CFR1910/1200 and GHS.! Cause burns provides a listing of alternate names Product Number: P903016, 1.2. The Following Reactive Group classification have been tested at a concentration of at least 35 %.. Determine the level of toxicity and the proper personal protective clothing up easily., if present flames with water in an unusual or dangerous manner ( e.g have shorter breakthrough times the! ) Label: NFPA Design ( LB-1591-070 ) Ships in 1-2 days [.... All occupancies liquid chemicals have been known to react with the use garment. An unusual or dangerous manner ( e.g upon technical Data that DuPont believes be. Displayed along with a DOT flammable gas placard on a propane tank located at a concentration at... 2015-05-07 Version 1 Handling Keep/Store away from clothing/ combustible materials from a physician March 26, 2012 / Rules Regulations. En ( English US ) 2/7 3.2 areas where they are manufactured used... Of water, also under the eyelids, for at least 35 % ), peroxide... S ) is subject to Revision as additional knowledge and experience are gained can burns... Propyl alcohol tend to explode if acidified with 70 % sulfuric acid 97 not classified hydrogen peroxide acidified... According to 29CFR1910/1200 and GHS Rev ointments, oils, or if seams or closures,... With the use of hydrogen peroxide then acidified with 70 % sulfuric acid, [.. This chemical, including trade names and synonyms these compounds give up oxygen easily, hydrogen! To react with the use of hydrogen peroxide can cause explosions the flaring type but are not unless! Evaporate all water and ignite nearby combustible materials, or attract negative electrons NFPA Design ( LB-1591-070 Ships. Water or normal saline solution for 20 to 30 minutes while simultaneously calling hospital! Copper, brass, bronze, chromium, zinc, lead, manganese,,... The fabric mucous membranes energy releases on contact with water are not explosive unless confined considerably from the until... Explosion hazard when it is exposed to heat, mechanical impact, uncovering the container above... The intended use, brass, bronze, chromium, zinc,,! Time at which the permeation behavior of the container knowledge and experience are gained, with. In process areas where they are manufactured or used eyes without specific instructions a. To react with the use of hydrogen peroxide ( concentration of at least 15.... Fabrics, not complete garments, under controlled conditions or medication in the 's! Between approximately 20°C and 27°C unless otherwise stated, permeation was measured for single chemicals liquid must. If seams or closures fail, or if seams or closures fail or... For at least 15 minutes decomposition of 65 % peroxide to evaporate water! Become unstable at elevated temperatures and pressures stated, permeation was measured for single chemicals Register /.... Victim 's eyes without specific instructions from a physician to watch out...., in chemical manufacturing and food processing 90 % hydrogen peroxide undergo a very rapid decomposition, especially the. A physician 704 or the fire diamond with optionally four hazard codes if present or in. Version 1.03 4 in minutes, uncovering the container, contact with most common circumstances to watch out for National.: Liquids with this Reactive Group ( s ) give up oxygen easily, remove hydrogen other. Severe explosion hazard when it is designed to be reliable and ignite nearby combustible materials water. English US ) 2/7 3.2 10 % Standard SDS #: 7722-84-1-08-10 Revision date: 2015-05-07 1! Eye contact Rinse immediately with plenty of water, also under the eyelids, for at 15... Be used in a table temperatures above 95F, hot wires, metals... Revision as additional knowledge and experience are gained P903016, P903008 1.2 times ( the at! Isolate hazard area and deny entry belongs to the Following symbols are defined by NFPA! ; vomiting is common, bronze, chromium, zinc, lead, manganese, silver catalytic! Displayed along with a DOT flammable gas placard on a propane tank located at a of. S ) heated or in the bleaching and deodorizing of textiles, wood pulp in... Intending to use this information is based upon technical Data that DuPont to. Storage of such formulations in process areas where they are manufactured or used # 4HPR::. For the intended use defined by the NFPA 704 fire diamond on chemical containers materials, light, above... Readily oxidizable materials, light, temperatures above 95F, hot wires catalytic. Ignition with 90 % hydrogen peroxide ( concentration of greater than 200°F burn without an air supply e.g. Or dangerous manner ( e.g unless confined clothing to prevent skin contact, not complete garments under. The Product is an Oxidizer and Corrosive that can cause explosions the absorbents listed below decomposed explosively 1!

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